Improving the efficiency of metal ions doped Fe2O3 nanoparticles: Photocatalyst for removal of organic dye from aqueous media.

The metal ion-based nanocomposite photocatalysts were accepted to exhibit a wide range of photocatalytic and biological applications. In this paper, we synthesize bare Fe2O3, 1 wt% metal (Ag, Co, and Cu) doped Fe2O3 nanoparticles (NPs) using a simple hydrothermal process and wet impregnation method. The as-prepared nanomaterials crystalline structure, shape, optical characteristics, and elemental composition were determined by using X-ray powder diffraction (XRD), X-ray photoelectron spectroscopy (XPS), Scanning electron microscope (SEM), Energy-dispersive X-ray (EDS) and Transmission electron microscopy (TEM) techniques. Furthermore, the synthesized nanocomposites were utilized as a photosensitizer for the degradation of reactive red (RR120) and orange II (O-II) dyes under sunlight irradiation. The synthesized 1 wt% Ag-Fe2O3 (AgF) NPs samples exhibit a more exceptional catalytic performance of RR120 and O-II dyes (98.32%) within 120 min than the existing Fe2O3, 1 wt% Co-Fe2O3, and Cu-Fe2O3 NPs. The effect of parameters such as exciton formation under solar irradiation, charge recombination rate, and surface charge availability. The metal oxide-doped nanocomposite economic relevance is revealed by their long-term durability and recyclability in photodegradation reactions. The photocatalytic investigations show that the active species O2∙-, HO∙ and h+ play an important role in the dye degradation process. This research might pave the opportunity for the sustainable development of greater photocatalysts for photodegradation and a wide range of environmental applications.

MoS2-ZnO Nanocomposite Mediated Immunosensor for Non-Invasive Electrochemical Detection of IL8 Oral Tumor Biomarker.

In order to support biomolecule attachment, an effective electrochemical transducer matrix for biosensing devices needs to have many specialized properties, including quick electron transfer, stability, high surface area, biocompatibility, and the presence of particular functional groups. Enzyme-linked immunosorbent assays, gel electrophoresis, mass spectrometry, fluorescence spectroscopy, and surface-enhanced Raman spectroscopy are common techniques used to assess biomarkers. Even though these techniques provide precise and trustworthy results, they cannot replace clinical applications because of factors such as detection time, sample amount, sensitivity, equipment expense, and the need for highly skilled individuals. For the very sensitive and targeted electrochemical detection of the salivary oral cancer biomarker IL8, we have created a flower-structured molybdenum disulfide-decorated zinc oxide composite on GCE (interleu-kin-8). This immunosensor shows very fast detection; the limit of detection (LOD) for interleukin-8 (IL8) detection in a 0.1 M phosphate buffer solution (PBS) was discovered to be 11.6 fM, while the MoS2/ZnO nanocomposite modified glassy carbon electrode (GCE) demonstrated a high catalytic current linearly from 500 pg to 4500 pg mL-1 interleukin-8 (IL8). Therefore, the proposed biosensor exhibits excellent stability, high accuracy sensitivity, repeatability, and reproducibility and shows the acceptable fabrication of the electrochemical biosensors to detect the ACh in real sample analysis.

Iron-engineered mesoporous biocarbon composite and its adsorption, activation, and regeneration approach for removal of paracetamol in water.

Three-dimensional multi-porous Iron Oxide/carbon (Fe2O3/C) composites derived from tamarind shell biomass were synthesized by a single-step co-pyrolysis technique and utilized for Paracetamol (PAC) dismissal in the combined adsorption, and advanced oxidation such as electrochemical regeneration techniques. The Fe2O3/C composites were prepared by different pyrolysis temperatures, and named as TS750 (without Fe2O3at 750 °C), MTS450 BCs (Low-450 °C), MTS600 BCs (Moderate-600 °C) and MTS750 BCs (high-750 °C), respectively. As-prepared Fe2O3/C composite was characterized by FE-SEM, XRD, BET, and XPS analysis. The specific surface area and the spatial interaction between the interlayers of Fe2O3 and C were significantly improved by increasing the pyrolysis temperatures from 450 to 750 °C, which improved the adsorption capacity of Fe2O3/C composites in terms of higher rate constants and chemisorption kinetics. The Pseudo-second-order kinetics model fitted in the adsorption test results of Fe2O3/C composites with the highest correlation co-efficiency. The Langmuir-isotherms model fitted in the adsorption test of the TS750 and MTS450 BCs. The Freundlich isotherms model is more fit with MTS600 and MTS750 BCs. Based on the isotherm results, the MTS750 BCs achieved 46.9 mg/g of maximum PAC adsorption capacity. The optimized MTS750 composites could be completely recovered by using an advanced electrochemical oxidation regeneration approach within 180 min. Also, with the adsorption and recovery process, the TOC removal rate improved to ∼79.4%. After the 6th cycle electrochemical oxidation process, the obtained results of the re-adsorption test showed the stabile adsorption activity of the sorbent material. The data outcomes herein propose that this type of combined adsorption and electrochemical approach will be useful in commercial water treatment plants.